| Crystal Structure of Calix［4］（dioxo） crown－6 Acetonitrile（1：3） Inclusion Complex |
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| 作者姓名： | ZHONG Zhen-Lin CHEN Yuan-Yin LU Xue-Ran |
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| 作者单位： | ZHONG Zhen-Lin; CHEN Yuan-Yin; LU Xue-Ran(Department of Chemistry，Wuhan University，Wuhan 430072)LUO Bao-Sheng;CHEN Liao-Rong(Center of Analytical Science，Wuhan University，Wuhan 430072) |
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| 摘 要： | ＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆＣａｌｉｘ［４］（ｄｉｏｘｏ）ｃｒｏｗｎ－６Ａｃｅｔｏｎｉｔｒｉｌｅ（１：３）ＩｎｃｌｕｓｉｏｎＣｏｍｐｌｅｘＺＨＯＮＧＺｈｅｎ－Ｌｉｎ；ＣＨＥＮＹｕａｎ－Ｙｉｎ；ＬＵＸｕｅ－Ｒａｎ（ＤｅｐａｒｔｍｅｎｔｏｆＣｈｅ...
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Crystal Structure of Calix[4](dioxo) crown-6 Acetonitrile(1:3) Inclusion Complex |
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| ZHONG Zhen-Lin, CHEN Yuan-Yin, LU Xue-Ran.Crystal Structure of Calix[4](dioxo) crown-6 Acetonitrile(1:3) Inclusion Complex[J].Chinese Journal of Structural Chemistry,1996(5). |
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| Authors: | ZHONG Zhen-Lin CHEN Yuan-Yin LU Xue-Ran |
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| Abstract: | The X-ray crystal structure of the inclusion complex of p-tert-butylcalix 4] crown-6 with actonitrile is reported. C54H70O10·3CH3CN, Mr=1002. 3 ,monoclinic, space group C2/c with cell dimensions of a=23.587(7),b=21.153(6),c=15.608(8) A,β=116.99(3)°,V=6939.2 A3,Z=4, F(000)=2160,Dc=0.959 g/cm3,μ=1.114 cm-1; R=0.088 for 2066 reflections with I>3σ(I).The calixarene subunit exists in a distorted cone conformation. One of the three acetonitrile molecules is located in the intracavity of the calixarene subunit and the other two in the intermolecular channels. |
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| Keywords: | crystal structure calixarene calixcrown acetonitrile inclusion complex |
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