| 混合溶剂中混合电解质活度系数的研究——HCl+NaCl+PrOH+H2O体系, 298.15 K |
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| 引用本文： | 初明晨,杨家振,梁春余,郑溪娟,诸若瑶.混合溶剂中混合电解质活度系数的研究——HCl+NaCl+PrOH+H2O体系, 298.15 K[J].物理化学学报,1985,1(5):476-481. |
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| 作者姓名： | 初明晨 杨家振 梁春余 郑溪娟 诸若瑶 |
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| 作者单位： | Department of Chemistry, Liaoning University, Shenyang |
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| 摘 要： |
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| 收稿时间： | 1984-10-22 |
| 修稿时间： | 1985-05-29 |
STUDIES OF ACTIVITY COEFFICIENTS OF MIXED ELECTROLYTES IN MIXED SOLVENTS System of HCI+NaCI+PrOH+H2O,at 298.15 K |
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| Chu Mingchen,Yang Jiazhen,Liang Chunyu,Zheng Xijuan,Zhu Ruoyao.STUDIES OF ACTIVITY COEFFICIENTS OF MIXED ELECTROLYTES IN MIXED SOLVENTS System of HCI+NaCI+PrOH+H2O,at 298.15 K[J].Acta Physico-Chimica Sinica,1985,1(5):476-481. |
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| Authors: | Chu Mingchen Yang Jiazhen Liang Chunyu Zheng Xijuan Zhu Ruoyao |
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| Institution: | Department of Chemistry, Liaoning University, Shenyang |
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| Abstract: | This paper reports our studies on HCl+NaCl+PrOH+H_2O system by mesns of emf measurements of the cell without liquid junction as type (A) Pt, H_2 (latm) |HCI (m_A), NaCl (m_B), PrOH(x), H_2O(1-x)| AgCl-Ag (A) at constant total ionic strengths I=0.1, 0.5, 1.0, 2.0 and 3.0 mol kg~(-1), at 298.15 K, where m_A and m_B are the molalities of HCl and NaCl, respectively, x is the molar fraction of PrOH in mixed solvents, x=0.05. The results show that HCI approximately follows Harned's Rule from I=0.1 to 3.0 mole kg~(-1)... |
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