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Ferric chloride catalyzed photooxidation of alkanes by air in organic solvents |
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| Authors: | G B Shulpin and M M Kats |
| Institution: | (1) Institute of Chemical Physics, 117977 Moscow, USSR |
| Abstract: | In the presence of catalytic amounts of FeCl3, alkanes (cyclohexane, n-hexane), toluene and ethylbenzene are oxidized by air oxygen to CH3CN, (CH3)2CO or CH2Cl2 under visible light irradiation to yield ketones and alcohols.
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