| Synthesis, Crystal Structure and Properties of [Co(1,3- bdoaH)_2·4H_2O]·4H_2O with Benzene-1,3-dioxyacetate Ligand |
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| 引用本文： | HUO Li-Hua GAO Shan LIU Ji-Wei ZHAO Hui ZHAO Jing-Gui (School of Chemistry and Materials Science,Heilongjiang University,Harbin 150080,China). Synthesis, Crystal Structure and Properties of [Co(1,3- bdoaH)_2·4H_2O]·4H_2O with Benzene-1,3-dioxyacetate Ligand[J]. 结构化学, 2005, 0(1) |
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| 作者姓名： | HUO Li-Hua GAO Shan LIU Ji-Wei ZHAO Hui ZHAO Jing-Gui (School of Chemistry and Materials Science Heilongjiang University Harbin 150080 China) |
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| 作者单位： | School of Chemistry and Materials Science，Heilongjiang University，Harbin 150080，China |
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| 基金项目： | This work was supported by the NNSF of China (No. 20101003)，NSF of Heilongjiang Province (No. B0007) and the Scientific Fund of Remarkable Teachers of Heilongjiang Province (grant No.1054G036) |
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| 摘 要： | 1INTRODUCTIONTheorganicaromaticcarboxylatemetalcom-plexeshavearousedmuchattentionandbeenwidelyinvestigated.However,thestrategyofdesignandsynthesisofthesecomplexesismostlyfocusedonrigidligands,suchasterephthalicacidandbenzenetricarboxylicacid,etc.[1～5].Theassemblyofcom-plexesbyusingflexiblearomaticcarboxylateli-gandsisfarlessdeveloped[6,.Phenylenedioxydia-7]ceticacids(bdoaH2)withbiologicalactivitiesandwideapplicationsinagriculture[8]areafamilyofmultidentateflexibleligandswithversatilebind…
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Synthesis,Crystal Structure and Properties of [Co(1,3- bdoaH)_2·4H_2O]·4H_2O with Benzene-1,3-dioxyacetate Ligand |
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| HUO Li-Hua GAO Shan LIU Ji-Wei ZHAO Hui ZHAO Jing-Gui. Synthesis,Crystal Structure and Properties of [Co(1,3- bdoaH)_2·4H_2O]·4H_2O with Benzene-1,3-dioxyacetate Ligand[J]. Chinese Journal of Structural Chemistry, 2005, 0(1) |
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| Authors: | HUO Li-Hua GAO Shan LIU Ji-Wei ZHAO Hui ZHAO Jing-Gui |
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| Abstract: | The cobalt(II) complex C20H34O20Co has been synthesized and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. The crystal belongs to triclinic, space group P1 with a = 5.1374(10), b = 10.519(2), c = 12.913(3) ?, α = 86.89(3), β = 79.94(3), γ = 86.74(3)o, V = 685.3(3) ?3, Z = 1, Mr = 653.40, Dc = 1.583 g/cm3, μ = 0.717 mm–1, F(000) = 341, the final R = 0.0657 and wR = 0.1141 for 1900 observed reflections with I > 2σ(I). The cobalt ion is six-coordinated by two O atoms of different 1,3-bdoaH– ligands and four water molecules, residing in an octahedral environment. The intermolecular hydrogen bonds form a 3-D supramolecular network structure. |
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| Keywords: | cobalt(II) carboxylate complex synthesis crystal structure |
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