首页 | 本学科首页   官方微博 | 高级检索  
     检索      


A photo Lewis acid generator (PhLAG): controlled photorelease of B(C6F5)3
Authors:Khalimon Andrey Y  Piers Warren E  Blackwell James M  Michalak David J  Parvez Masood
Institution:Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, Alberta, T2N 1N4 Canada.
Abstract:A molecule that releases the strong organometallic Lewis acid B(C(6)F(5))(3) upon irradiation with 254 nm light has been developed. This photo Lewis acid generator (PhLAG) now enables the photocontrolled initiation of several reactions catalyzed by this important Lewis acid. Herein is described the synthesis of the triphenylsulfonium salt of a carbamato borate based on a carbazole function, its establishment as a PhLAG, and the application of the photorelease of B(C(6)F(5))(3) to the fabrication of thin films of a polysiloxane material.
Keywords:
本文献已被 PubMed 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号