Redox-responsive morphology transformation of self-assembled nanostructures based on thiol-disulfide interconversion |
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| Authors: | Zhi-Gang TaoZe-Yun Xiao Xin Zhao Xi-Kui JiangZhan-Ting Li |
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| Affiliation: | State Key Lab of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China |
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| Abstract: | One dimensional (1D) nanotubes and three dimensional (3D) flowerlike supernanostructures were transformed reversibly, which was controlled by the oxidation and reduction cycle of aromatic diamide-derived thiol 1 and disulfide 2, as evidenced by SEM study. Their self-assembling patterns were investigated by UV-vis, 1H NMR, X-ray crystallographic, and powder X-ray diffraction experiments. |
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| Keywords: | Redox-responsive Self-assembly Nanostructures Thiol-disulfide interconversion Morphology transformation |
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