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A concise total synthesis of (+)-deoxocassine and (−)-deoxoprosophylline from d-xylose |
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| Authors: | Ch. KishoreA. Srinivas Reddy J.S. YadavB.V. Subba Reddy |
| Affiliation: | Natural products Chemistry, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
| Abstract: | A concise total synthesis of (+)-deoxocassine (1) and (−)-deoxoprosophylline (2) has been achieved for the first time from d-xylose. The key steps involved in these synthesis are alkyl Grignard reaction, SN2 substitution of mesylate by azide, Wittig reaction, and reductive amination. |
| Keywords: | Piperidine alkaloids smallcaps" >d-Xylose Natural products SN2 substitution Reductive amination |
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