Synthesis of (-)-agelastatin A by [3.3] sigmatropic rearrangement of allyl cyanate |
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| Authors: | Ichikawa Yoshiyasu Yamaoka Tomonori Nakano Keiji Kotsuki Hiyoshizo |
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| Affiliation: | Faculty of Science, Kochi University, Kochi 780-8520, Japan. ichikawa@kochi-u.ac.jp |
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| Abstract: | Total synthesis of (-)-agelastatin A has been achieved starting from l-arabitol. The highlights in our synthesis include the preparation of vicinal diamine moiety by [3.3] sigmatropic rearrangement of allyl cyanate and construction of central ring-C with ring-closing metathesis. |
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