Recoil reactions of38Cl and128I in some heterocyclic systems |
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Authors: | V G Dedgaonkar S Mitra Sunil Waghmare |
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Institution: | (1) Department of Chemistry, University of Poona, 411 007 Pune, India |
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Abstract: | Halogen recoil following /n, / reaction has been studied in some heterocyclic systems. The organic yields are 60% for irradiation as solids: exceptions are dioxanide furoate /34%/ and 5-chloro isatoic anhydride /31%/. As solutions in 11 THF + benzene and 11 HTF+DMSO, these yields are lower by 10% and decrase further when only THF is the solvent. Mass-spectroscopy data revealed the possible fragmentation pattern. |
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