Organosolv-pulping III |
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Authors: | Jaime Baeza Ana Maria Fernández Juanita Freer Ana Pedreros Eckhard Schmidt Nelson Durán |
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Institution: | 1. Departmento de Quimica, Renewable Resources Laboratory, Universidad de Conception, Casilla 3-C, Conception, Chile 2. Instituto de Quimica, Biological Chemistry Laboratory, Universidade Estadual de Campinas, C.P. 6154, CEP 13081, S.P., Campinas, Brazil
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Abstract: | Formic acid pretreatment onPinus radiata D. Don was studied in order to improve the cellulose hydrolysis by commercial cellulase. The formic acid treatment effectively
removed the lignin. A low substitution (formylation) and a crystallinity decrease of the cellulose in the pulp were observed.
As consequence of these parameter changes, owing to the formic acid pretreatment on sawdust, a higher saccharification value
was observed. The degree of saccharification increased when the degree of substitution (measured by titration) decreased and
the portion of amorphous cellulose (measured via an X-ray technique) increased.Trichoderma reesei cellulase hydrolyzed the untreated and pretreated Pinus sawdust with formic acid in 25% and 56% of saccharification, respectively. |
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Keywords: | Index Entries" target="_blank">Index Entries Organosolv pulping enzymatic hydrolysis formic acid delignification Pinus radiata |
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