9H‐Quinolino[3,2,1‐k]phenothiazine: A New Electron‐Rich Fragment for Organic Electronics |
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Authors: | Dr. Cyril Poriel Dr. Joëlle Rault‐Berthelot Dr. Sébastien Thiery Dr. Cassandre Quinton Dr. Olivier Jeannin Urelle Biapo Dr. Denis Tondelier Bernard Geffroy |
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Affiliation: | 1. UMR CNRS 6226-ISCR-, Université de Rennes 1, Rennes cedex, France;2. LPICM, CNRS, Ecole Polytechnique, Université Paris Saclay, Palaiseau, France;3. LICSEN, NIMBE, CEA, CNRS, Université Paris-Saclay, CEA Saclay, Gif-sur-Yvette Cedex, France |
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Abstract: | A new electron‐rich fragment, namely the quinolinophenothiazine (QPTZ) is reported. The QPTZ fragment incorporated in spiroconfigured materials leads to higher performance in blue Phosphorescent OLEDs than structurally related phenylacridine and indoloacridine based materials (increasing the HOMO energy level, modulating the spin‐orbit coupling, etc.) and leads to highly efficient blue phosphorescent organic light emitting diodes, indicating the strong potential of this new molecular fragment in organic electronics. |
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Keywords: | organic light-emitting diodes organic semiconductors quinolinophenothiazine spiro compounds |
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