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9H‐Quinolino[3,2,1‐k]phenothiazine: A New Electron‐Rich Fragment for Organic Electronics
Authors:Dr. Cyril Poriel  Dr. Joëlle Rault‐Berthelot  Dr. Sébastien Thiery  Dr. Cassandre Quinton  Dr. Olivier Jeannin  Urelle Biapo  Dr. Denis Tondelier  Bernard Geffroy
Affiliation:1. UMR CNRS 6226-ISCR-, Université de Rennes 1, Rennes cedex, France;2. LPICM, CNRS, Ecole Polytechnique, Université Paris Saclay, Palaiseau, France;3. LICSEN, NIMBE, CEA, CNRS, Université Paris-Saclay, CEA Saclay, Gif-sur-Yvette Cedex, France
Abstract:A new electron‐rich fragment, namely the quinolinophenothiazine (QPTZ) is reported. The QPTZ fragment incorporated in spiroconfigured materials leads to higher performance in blue Phosphorescent OLEDs than structurally related phenylacridine and indoloacridine based materials (increasing the HOMO energy level, modulating the spin‐orbit coupling, etc.) and leads to highly efficient blue phosphorescent organic light emitting diodes, indicating the strong potential of this new molecular fragment in organic electronics.
Keywords:organic light-emitting diodes  organic semiconductors  quinolinophenothiazine  spiro compounds
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