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The racemate cage. Influence of p(1),n(1) salt occurrence on enantiomer separation processes. The case of trans-chrysanthemic acid
Authors:Rosini Goffredo  Borzatta Valerio  Boschi Francesca  Candido Gabriele  Marotta Emanuela  Righi Paolo
Institution:Dipartimento di Chimica Organica "A. Mangini", Alma Mater Studiorum--Università di Bologna, V.le del Risorgimento 4, 40136 Bologna, Italy. goffredo.rosini@unibo.it
Abstract:The occurrence of p(1),n(1) salt when accompanied by substrate self-association can have profound effects on enantiomer separation processes of non-racemic mixtures, impeding the complete recovery of the major enantiomer through formation of an inescapable racemate cage.
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