| 钼多金属氧酸盐催化微晶纤维素水解制备葡萄糖的研究 |
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| 引用本文： | 杨浩天,周娴,杨可,刘佳美,邹杨杨,陈佳庆,王景芸,周明东. 钼多金属氧酸盐催化微晶纤维素水解制备葡萄糖的研究[J]. 化学通报, 2019, 82(9): 855-859 |
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| 作者姓名： | 杨浩天 周娴 杨可 刘佳美 邹杨杨 陈佳庆 王景芸 周明东 |
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| 作者单位： | 辽宁石油化工大学化学化工与环境学部 抚顺 113001;辽宁石油化工大学化学化工与环境学部 抚顺 113001;辽宁石油化工大学化学化工与环境学部 抚顺 113001;辽宁石油化工大学化学化工与环境学部 抚顺 113001;辽宁石油化工大学化学化工与环境学部 抚顺 113001;辽宁石油化工大学化学化工与环境学部 抚顺 113001;辽宁石油化工大学化学化工与环境学部 抚顺 113001;辽宁石油化工大学化学化工与环境学部 抚顺 113001 |
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| 基金项目： | 辽宁省自然科学基金(20170540590); 辽宁省教育厅基本科研项目(L2017LFW011);中国石油科技创新基金研究项目(2018D-5007-0507);辽宁石油化工大学博士科研启动基金(2016XJJ-063) |
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| 摘 要： | 合成了8种基于Mo8O26的钼多金属氧酸盐,采用红外(FT-IR)和核磁共振(NMR)对其结构进行表征,并将其应用于催化纤维素水解。以离子液体1-烯丙基-3-甲基咪唑氯盐([Amim]Cl)为溶剂进行微晶纤维素(MCC)水解反应,考察催化剂及其用量、反应温度、反应时间等条件对水解反应的影响。研究结果表明,本文所制备的钼多金属氧酸盐对微晶纤维素水解反应均具有较好的催化活性。在微波辅助加热条件下,当催化剂[(CH3)4N]4Mo8O26用量为10 wt%,在170 ℃反应20 min时,纤维素可完全转化,微晶纤维素TRS和葡萄糖收率最高分别为84.5% 和41.5 %。
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| 关 键 词： | 钼多金属氧酸盐 纤维素 水解 葡萄糖 |
| 收稿时间： | 2019-03-10 |
| 修稿时间： | 2019-06-12 |
Hydrolysis of cellulose to glucose catalyzed by molybdenum polyoxometalates |
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| Yang Haotian,Zhou Xian,Yang Ke,Liu Jiamei,Zou Yangyang,Chen Jiaqing,Wang Jingyun and Zhou Mingdong. Hydrolysis of cellulose to glucose catalyzed by molybdenum polyoxometalates[J]. Chemistry, 2019, 82(9): 855-859 |
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| Authors: | Yang Haotian Zhou Xian Yang Ke Liu Jiamei Zou Yangyang Chen Jiaqing Wang Jingyun Zhou Mingdong |
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| Affiliation: | College of Chemistry,Chemical Engineering and Environmental Engineering,Liaoning Shihua University,College of Chemistry,Chemical Engineering and Environmental Engineering,Liaoning Shihua University,College of Chemistry,Chemical Engineering and Environmental Engineering,Liaoning Shihua University,College of Chemistry,Chemical Engineering and Environmental Engineering,Liaoning Shihua University,College of Chemistry,Chemical Engineering and Environmental Engineering,Liaoning Shihua University,College of Chemistry,Chemical Engineering and Environmental Engineering,Liaoning Shihua University,College of Chemistry,Chemical Engineering and Environmental Engineering,Liaoning Shihua University,College of Chemistry,Chemical Engineering and Environmental Engineering,Liaoning Shihua University |
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| Abstract: | 8 kinds of Mo8O26 based compounds were synthesized and the structure of these compounds were characterized by NMR and FT-IR. Microcrystalline cellulose was hydrolyzed to produce the total reducing sugar (TRS) in ionic liquid [Amim]Cl using molybdenum polyoxometalate as catalyst under microwave irradiation conditions.The effects of catalyst and its dosage, reaction temperature and reaction time on the hydrolysis reaction were investigated. The results indicated that the molybdenum polyoxometalates prepared in this paper have good catalytic activity for the hydrolysis reaction of microcrystalline cellulose. The cellulose can be completely converted with the addition of 10wt% of catalyst [(CH3)4N]4Mo8O26 under the microwave-assisted heating condition in the ionic liquid [Amim]Cl at 170 ° C for 20 min. The highest TRS and glucose yields of MCC were 84.5 % and 41.5% respectively. |
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| Keywords: | Molybdenum polyoxometalates Cellulose Hydrolysis Glucose |
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