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Convenient preparation of trans-arylalkenes via palladium(II)-catalyzed isomerization of cis-arylalkenes
Authors:Yu Jinquan  Gaunt Matthew J  Spencer Jonathan B
Affiliation:University Chemical Laboratory, Lensfield Road, Cambridge CB2 1EW, UK.
Abstract:A convenient method for the isomerization of cis-arylalkenes to their trans isomers using a palladium(II) catalyst is described. The reaction conditions are mild and general across a range of arylalkenes. The synthesis of a trans-resveratrol derivative from a mixture of alkene isomers was also completed.
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