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对苯二酚在K_2CO_3-Al_2O_3负载型碱试剂作用下的单醚化反应
引用本文:张智勇,陆婉芳,旅耀曾,陈晋苏. 对苯二酚在K_2CO_3-Al_2O_3负载型碱试剂作用下的单醚化反应[J]. 应用化学, 1994, 0(5)
作者姓名:张智勇  陆婉芳  旅耀曾  陈晋苏
作者单位:南京大学化学系
基金项目:江苏省科委和国家自然科学基金资助课题
摘    要:在K_2CO_3-Al_2O_3负载型碱试剂作用下,对苯二酚可发生选择性的单醚化反应.单醚产率高,操作简便.文中讨论了影响单醚产率的各种反应条件和可能的反应机理.

关 键 词:对苯二酚,醚化反应,K_2CO_3-Al_2O_3试剂

Monoetherification of Hydroquinone Under the Action of Al_2O_3-supported K_2CO_3 Reagent
Zhang Zhiyong,Lu Wanfang,Shi Yaozeng and Chen Jingsu. Monoetherification of Hydroquinone Under the Action of Al_2O_3-supported K_2CO_3 Reagent[J]. Chinese Journal of Applied Chemistry, 1994, 0(5)
Authors:Zhang Zhiyong  Lu Wanfang  Shi Yaozeng  Chen Jingsu
Abstract:By using Al2O3-supported K2CO3 as a base reagent,the highly selective mo-noetherification of hydroquinone by alkylating reagents has been carried out in good yield andby simple experimental procedures.A variety of reaction conditions affecting the monoethe-rification and a probable reaction mechanism were discussed.
Keywords:hydroquinone  etherification  K_2CO_3-Al_2O_3 reagent
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