Total synthesis of marine bisindole alkaloids, (+)-hamacanthins A, B and (−)-antipode of cis-dihydrohamacanthin B |
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| Authors: | Takashi Kouko |
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| Institution: | Meiji Pharmaceutical University, 2-522-1 Noshio Kiyose, Tokyo 204-8588, Japan |
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| Abstract: | The total synthesis of the marine bisindole alkaloids, (+)-hamacanthins A (2a) and B (2b), and (−)-antipode of cis-dihydrohamacanthin B (2e) was achieved by transamidation-cyclization of N-(2-aminoethyl)-2-oxoethanamide 18 derived from (S)-indolylglycinol 10. |
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| Keywords: | Bromoindole Indolylglycinol Oxazolidin-2-one Absolute configuration |
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