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Chemical transformation of Baylis-Hillman adducts: the reaction of methyl 3-arylamino-2-methylene-3-phenylpropanoates in polyphosphoric acid
Authors:Chang Gon Lee  Sangku Lee
Affiliation:a Department of Chemistry and Institute of Basic Science, Chonnam National University, Gwangju 500-757, South Korea
b Korea Research Institute of Bioscience and Biotechnology, 52 Oun, Yusong, Taejon 305-333, South Korea
Abstract:We synthesized some interesting compounds including 3-benzylidene-3,4-dihydro-1H-quinolin-2-one, 3-benzylquinolin-2-ol, 4-amino-2-benzylideneindan-1-one, and 1-amino-9a,10-dihydro-4bH-indeno[1,2-a]inden-9-one skeletons starting from Baylis-Hillman adducts.
Keywords:Baylis-Hillman adducts   Polyphosphoric acid (PPA)   Quinolin-2-ones   Quinolin-2-ols   Indan-1-ones   Indeno[1,2-a]inden-9-ones
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