Studies on alkylation of bicyclo[2.2.2]octenones and 3,3-sigmatropic shift: synthesis of advanced cis-decalins |
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| Authors: | Vishwakarma Singh Sridhar R Iyer |
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| Institution: | Department of Chemistry, Indian Institute of Technology Bombay, Mumbai 400 076, India |
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| Abstract: | A stereoselective method for alkylation of bicyclo2.2.2]octenones and their 3,3-sigmatropic shift leading to cis-decalins containing various types of appendages is described. A simple and convenient method for the introduction of a butenyl chain onto the bicyclooctenones employing 1,4-dibromobutane as an equivalent of 4-bromobutene, was developed. |
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| Keywords: | Bicyclo[2 2 2]octenones cis-Decalin [3 3]-Sigmatropic shift Alkylation |
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