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Lead(II)-selective ionophores for ion-selective electrodes: A review
Authors:Marcin Guziński  Grzegorz Lisak  Justyna Kupis  Artur Jasiński  Maria Bocheńska
Affiliation:1. Department of Chemical Technology, Chemical Faculty, Gdańsk University of Technology, Narutowicza 11/12, 80-233 Gdańsk, Poland;2. Laboratory of Analytical Chemistry, Process Chemistry Centre, Åbo Akademi University, Biskopsgatan 8, FI-20500 Åbo/Turku, Finland;3. AGH – University of Science and Technology, Faculty of Materials Science and Ceramics, Mickiewicza 30, 30-059 Cracow, Poland
Abstract:In potentiometry, high selectivity of the ion-selective membranes must be assured in order to reliably measure various analytes in clinical, industrial and environmental samples. Due to the toxic nature of lead(II) it is important to monitor Pb2+ distribution in natural waters. This may be achieved by implementation of ion-selective electrodes (ISEs) with high selectivity towards lead(II) and low detection limit. A great number of Pb2+-ionophores were synthesized and studied. In this work lead(II)-selective ionophores, starting from late 90s, are gathered and discussed. This work gives a comprehensive description and discussion on the novel and available lead(II)-selective ionophores for ISEs.
Keywords:Ionophores   Selectivity of ion-selective electrodes
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