| 内-α-取代-α-甲基双环[2,2,1]庚烷-2-基甲醇的合成及其结构与香气的关系 |
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| 引用本文： | 汪小兰,唐士雄,游少春,王长凤,曹玉蓉. 内-α-取代-α-甲基双环[2,2,1]庚烷-2-基甲醇的合成及其结构与香气的关系[J]. 高等学校化学学报, 1989, 0(1) |
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| 作者姓名： | 汪小兰 唐士雄 游少春 王长凤 曹玉蓉 |
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| 作者单位： | 南开大学化学系(汪小兰，唐士雄，游少春，王长凤)，南开大学化学系(曹玉蓉) |
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| 摘 要： | 合成了18种内-α-取代-α-甲基双环[2,2,1]庚烷-2-基甲醇(Ⅰ)。测定了所有化合物的折光率(或熔点)、质谱、红外光谱、~1H核磁共振谱、气相色谱的保留时间和薄层色谱的比移值。评定了它们的香气,并与相应的内-α-取代-α-甲基双环[2,2,1]-5-庚烯-2-基甲醇(Ⅱ)系列化合物的香气进行了比较,初步探讨了结构与香气的关系。
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| 关 键 词： | 内-α-取代-α-甲基双环[2 2 1]庚烷-2-基甲醇 合成 香气 |
Syntheses of Some Endo-o-Substituted-o-methyl Bicyclo[2,2,1]heptane-2-methanols and Relations Between Their Structures and Odors |
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| Wang Xiaolan,Tang Shixiong,You Sbaocbun,Wang Cbangfeng,Cao Yurong. Syntheses of Some Endo-o-Substituted-o-methyl Bicyclo[2,2,1]heptane-2-methanols and Relations Between Their Structures and Odors[J]. Chemical Research In Chinese Universities, 1989, 0(1) |
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| Authors: | Wang Xiaolan Tang Shixiong You Sbaocbun Wang Cbangfeng Cao Yurong |
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| Abstract: | Eighteen title compounds were synthesized. The refractive indices (or melting points), retention times in GLC, Rf in TLC, MS, IR and 1H NMR spectra of these compounds were obtained. Their olfactory characteristics were evaluated and compared with endo-a-substituted-a-methylbicyclo[2, 2, 1]hept-5-ene-2-methanols. The relations between structures and odors were discussed. |
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| Keywords: | Endo-a-Substituted-a-methylbicyclo[2 2 1]heptane-2-methanol Synthesis Odor |
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