| 氧族元素间共价单键参与的无机反应机理 |
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| 引用本文： | 马明哲,曹若辰,武江波,徐佳宇,卞江. 氧族元素间共价单键参与的无机反应机理[J]. 大学化学, 2017, 32(10): 75-83. DOI: 10.3866/PKU.DXHX201703017 |
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| 作者姓名： | 马明哲 曹若辰 武江波 徐佳宇 卞江 |
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| 作者单位： | 1. 北京大学元培学院,北京,100871;2. 北京大学化学与分子工程学院,北京,100871 |
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| 摘 要： | 结合一些热力学数据和动力学过程,运用亲电和亲核的概念,初步阐释了一些O―O键、S―S键参与的氧化还原反应的机理,并利用Gaussian09程序的计算对一些已有的机理和猜想进行了验证,以此说明无机反应机理的一些规律。
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| 关 键 词： | 无机反应机理 氧族元素 Ch-Ch键(Ch是Chalcogen (氧族元素)的缩写) 氧化还原反应 |
Inorganic Reaction Mechanism of Chalcogen-Chalcogen Bond |
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| MA Ming-Zhe,CAO Ruo-Chen,WU Jiang-Bo,XU Jia-Yu,BIAN Jiang. Inorganic Reaction Mechanism of Chalcogen-Chalcogen Bond[J]. University Chemistry, 2017, 32(10): 75-83. DOI: 10.3866/PKU.DXHX201703017 |
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| Authors: | MA Ming-Zhe CAO Ruo-Chen WU Jiang-Bo XU Jia-Yu BIAN Jiang |
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| Affiliation: | 1. College of Yuanpei, Peking University, Beijing 100871, P. R. China;2. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China |
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| Abstract: | This paper explains some inorganic reaction mechanisms of oxidation-reduction reactions involving chalcogen-chalcogen single bond, according to thermodynamic and kinetic data. DFT method is used to verify proposed mechanisms and conjectures by Gaussian09 program. All these efforts are put to demonstrate some general patterns in inorganic reaction mechanisms. |
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| Keywords: | Inorganic reaction mechanism Chalcogen Chalcogen-chalcogen bond Oxidation-reduction reaction |
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