| Preparation and X-ray Crystal Structure of Di-chlorobis (p-t-butylphenylbutyl Sulfide)Palladium(Ⅱ) |
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| 作者单位： | Chemistry and Chemical Engineering College, Suzhou University, Suzhou, 215006 |
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| 摘 要： | ＮＴＲＯＤＵＣＴＩＯＮＩｔｉｓｋｎｏｗｎｔｈａｔｄｉａｌｋｙｌｓｕｌｆｉｄｅｓａｒｅｅｆｅｃｔｉｖｅｅｘｔｒａｃｔａｎｔｓｆｏｒｔｈｅｅｘｔｒａｃｔｉｏｎａｎｄｓｅｐａｒａ ｔｉｏｎｏｆｎｏｂｌｅｍｅｔａｌｓ〔１，２〕．Ｐａｌａｄｉｕｍｃｏｍｐｌｅｘ...
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| 关 键 词： | Pd(Ⅱ) complex |
Preparation and X-ray Crystal Structure of Di-chloro-bis(p-t-butylphenylbutyl Sulfide) Palladium(Ⅱ) |
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| ZHAO Bei,GUO Song-Shan,WANG Han-Zhang,YU Kai-Bei. Preparation and X-ray Crystal Structure of Di-chloro-bis(p-t-butylphenylbutyl Sulfide) Palladium(Ⅱ)[J]. Chinese Journal of Structural Chemistry, 1999, 18(1) |
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| Authors: | ZHAO Bei GUO Song-Shan WANG Han-Zhang YU Kai-Bei |
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| Abstract: | PdCl2[(CH3)3CC6H4SC4H9-S]2, C28H44Cl2S2Pd, Mr=622.0756, triclinic, space group P, a=10.403(2), b=12.346(2), c=13.475(2)(), α=89.11(1)°, β=75.44(1)°, γ=69.52(1)°, V=1564.2(5) 3, Z=2, Dc=1.32 g/cm3, MoKα radiation, μ=9.00 cm-1, F(000)=647.95, R=0.0316 for 4561 observed reflections with I≥3σ(I). Pd(Ⅱ) is coordinated by two chloride atoms and two sulfur atoms of organic ligands, forming a rhombic-quadrilateral plane with Pd-S of 2.325(1)()and Pd-Cl of 2.295(1)(). |
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| Keywords: | p-t-butylphenylbutyl sulfide chloro-t-butylphenylbutyl-sulfide-palladium |
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