An α‐{P2W18O62}6–‐Based Supramolecular Hybrid Inorganic‐Organic Compound with Visible Light‐Driven Photocatalytic Properties |
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| Authors: | Xiaofei Zhu Yu Yang Ni Jiang Bo Li Hai Fu Zifan Yin Jun Yang |
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| Institution: | 1. School of Chemistry and Life Science, Changchun University of Technology, Changchun, Jilin, 130012, P. R. China;2. Hebei Provincial Key Laboratory of Inorganic Nonmetallic Materials, College of Materials Science and Engineering, College of Public Health, North China University of Science and Technology, Tangshan 063009, P. R. China |
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| Abstract: | The α‐P2W18O62]6–‐based coordination polymer Cu2(phen)3(H2O)3(P2W18O62)]Cu(phen)2(H2O)] · 5H2O ( 1 ) (phen = phenanthroline), was hydrothermally synthesized and characterized by single‐crystal and powder X‐ray diffraction, IR and UV/Vis diffuse reflection spectroscopy, and elemental analysis. Structural studies reveal that compound 1 exhibits a three‐dimensional (3D) supramolecular structure based on π–π and hydrogen bonding interactions. In addition, visible light driven photocatalytic experiments of compound 1 were also studied. |
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| Keywords: | Coordination polymer Crystal structure Visible light Photocatalytic properties Tungsten |
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