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An α‐{P2W18O62}6–‐Based Supramolecular Hybrid Inorganic‐Organic Compound with Visible Light‐Driven Photocatalytic Properties
Authors:Xiaofei Zhu  Yu Yang  Ni Jiang  Bo Li  Hai Fu  Zifan Yin  Jun Yang
Institution:1. School of Chemistry and Life Science, Changchun University of Technology, Changchun, Jilin, 130012, P. R. China;2. Hebei Provincial Key Laboratory of Inorganic Nonmetallic Materials, College of Materials Science and Engineering, College of Public Health, North China University of Science and Technology, Tangshan 063009, P. R. China
Abstract:The α‐P2W18O62]6–‐based coordination polymer Cu2(phen)3(H2O)3(P2W18O62)]Cu(phen)2(H2O)] · 5H2O ( 1 ) (phen = phenanthroline), was hydrothermally synthesized and characterized by single‐crystal and powder X‐ray diffraction, IR and UV/Vis diffuse reflection spectroscopy, and elemental analysis. Structural studies reveal that compound 1 exhibits a three‐dimensional (3D) supramolecular structure based on π–π and hydrogen bonding interactions. In addition, visible light driven photocatalytic experiments of compound 1 were also studied.
Keywords:Coordination polymer  Crystal structure  Visible light  Photocatalytic properties  Tungsten
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