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Synthesis and Molecular Structure of trans‐[IrCl(NO)(PtBu2H)2]BF4
Authors:Hans‐Christian Böttcher  Thomas Mies  Peter Mayer
Affiliation:Department Chemie, Ludwig‐Maximilians‐Universit?t, Butenandtstr. 5–13 (D), 81377 München, Germany
Abstract:The synthesis and structural characterization of trans‐[IrCl(NO)(PtBu2H)2]BF4 ( 1 ) is reported. The title compound was prepared in good yield in the reaction of in situ‐prepared trans‐[IrCl(coe)(PtBu2H)2] (coe = cis‐cyclooctene) with an appropriate amount of nitrosonium tetrafluoridoborate in dichloromethane at room temperature. Single crystals of 1 were grown from dichloromethane/diethyl ether and were analyzed by X‐ray crystallography.
Keywords:Nitrosyl complexes  Iridium  Secondary phosphanes  Crystal structure
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