Synthesis and Molecular Structure of trans‐[IrCl(NO)(PtBu2H)2]BF4 |
| |
| Authors: | Hans‐Christian Böttcher Thomas Mies Peter Mayer |
| |
| Institution: | Department Chemie, Ludwig‐Maximilians‐Universit?t, Butenandtstr. 5–13 (D), 81377 München, Germany |
| |
| Abstract: | The synthesis and structural characterization of trans‐IrCl(NO)(PtBu2H)2]BF4 ( 1 ) is reported. The title compound was prepared in good yield in the reaction of in situ‐prepared trans‐IrCl(coe)(PtBu2H)2] (coe = cis‐cyclooctene) with an appropriate amount of nitrosonium tetrafluoridoborate in dichloromethane at room temperature. Single crystals of 1 were grown from dichloromethane/diethyl ether and were analyzed by X‐ray crystallography. |
| |
| Keywords: | Nitrosyl complexes Iridium Secondary phosphanes Crystal structure |
|
