Lanthanides Mediated Oxidative Cross Coupling of Benzylalcohol and Various Amines to Form Corresponding Imines
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| Authors: | Jayeeta Bhattacharjee Mitali Sachdeva Tarun K Panda |
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| Institution: | Department of Chemistry, Indian Institute of Technology, Hyderabad 502285, Telangana, India |
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| Abstract: | Herein, a new and efficient approach towards the oxidative cross‐coupling of benzylalcohol and various aromatic amines to form corresponding imines with high degree conversion (>80 %) and chemo‐selectivity using lanthanide salts as pre‐catalysts is presented. The catalyzed oxidative cross‐coupling reaction using La(NO3)3 · 6H2O as pre‐catalyst displayed a broad substrate scope. The reaction afforded various substituted imines from the reaction of benzylalcohol with ample variety of amines in good yields. |
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| Keywords: | Lanthanides Alcohols Cross‐coupling Imines Catalysis |
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