Manganese‐σ‐Borane Complexes from Dihaloboranes |
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| Authors: | Prof Dr Holger Braunschweig Katharina Kraft Thomas Kupfer Eva Siedler |
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| Institution: | Universit?t Würzburg, Institut für Anorganische Chemie, Am Hubland, 97074 Würzburg, Germany |
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| Abstract: | The hydride complex K(η5‐C5H5)Mn(CO)2H] reacted with a range of dihalo(organyl)boranes X2BR (X = Cl, Br; R = tBu,Mes, Ferrocenyl) to give the corresponding borane complexes(η5‐C5H5)Mn(CO)2(HB(X)R)]., The presence of a hydride in bridging position between manganese and boron was deduced from 11B decoupled 1H NMR spectra. Additionally, the structure of the tert‐butyl borane complex was confirmed by single‐crystal X‐ray diffraction. |
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| Keywords: | Boron Manganese Boryl complexes Borane complexes Halogenes |
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