K3[C3N3(COO)3]·2H2O – Crystal Structure of a New Alkali Derivative of the Multidentate Ligand Triazine Tricarboxylate |
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Authors: | Sophia  J. Makowski,Michael Hörmannsdorfer,Prof. Dr. Wolfgang Schnick |
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Affiliation: | Department Chemie, Lehrstuhl für Anorganische Festk?rperchemie, Ludwig‐Maximilians‐Universit?t München, Butenandtstra?e 5–13 (D), 81377 München, Germany |
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Abstract: | Potassium‐1,3,5‐triazine‐2,4,6‐tricarboxylate dihydrate K3[C3N3(COO)3] · 2H2O was obtained by saponification of the respective ethyl ester in aqueous solution under mild conditions and subsequent crystallization at 4 °C. The crystal structure of the molecular salt was elucidated by single‐crystal X‐ray diffraction [P , a = 696.63(14), b = 1748.5(3), c = 1756.0(3) pm, α = 119.73(3), β = 91.96(3), γ = 93.84(3)°, V = 1847.6(6) · 106 pm3, Z = 6, T = 200 K]. Perpendicular to [100] the triazine tricarboxylate and potassium ions are arranged in layers alternating with layers of crystal water molecules. Two thirds of the triazine tricarboxylate units form hexagonal channels being filled with the remaining triazine tricarboxylate molecules. K3[C3N3(COO)3] · 2H2O was additionally investigated by means of FTIR spectroscopy, TG and DTA measurements. |
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Keywords: | s‐Triazine Potassium Carboxylate ligands Structure elucidation Metal‐organic frameworks |
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