Solvothermal Synthesis of New Luminescent Zinc(II) Coordination Polymers with One‐Dimensional Homochiral Structures |
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| Authors: | Yulai Duan Dr Zhien Lin Tobias Stips Prof Dr Stefanie Dehnen |
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| Institution: | 1. College of Chemistry, Sichuan University, Chengdu 610064, P. R. China;2. Fachbereich Chemie, Wissenschaftliches Zentrum für Materialwissenschaften, Philipps‐Universit?t Marburg, Hans‐Meerwein‐Strasse, 35043 Marburg, Germany |
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| Abstract: | By using a dual‐ligand approach, two new homochiral zinc(II) coordination polymers, Zn2(phen)2(H2O)2(cam)2 · ethanol ( 1 ) and Zn(bipy)(cam) ( 2 ) phen = 1,10‐phenanthroline, bipy = 2,2′‐bipyridine, H2cam = (1R,3S)‐(+)‐camphoric acid] have been synthesized under solvothermal conditions. Compound 1 has a zigzag chain‐like structure and compound 2 has a linear chain‐like structure. The two compounds exhibit intense photoluminescence upon photoexcitation at 280 and 290 nm, respectively. |
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| Keywords: | Solvothermal synthesis Luminescence Zinc Coordination polymers Homochiral structures |
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