Oxidation of Formic and Oxalic Acids in an Electrodeless Electrochemical Reaction |
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| Authors: | Aristova N A Mokina T S Piskarev I M |
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| Institution: | (1) Nizhny Tagil Institute of Technology, Ural State Technical University, Nizhny Tagil, Sverdlovsk oblast, Russia;(2) Skobel'tsyn Research Institute of Nuclear Physics, Moscow State University, Moscow, Russia |
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| Abstract: | Decomposition of formic and oxalic acid and of sodium formate and sodium oxalate ( 0.1 M solutions) in an electrodeless electrochemical reaction was studied. The oxidation kinetics was analyzed in terms of the previously developed model. The decomposition yields of formic acid and sodium formate are 0.5 and 1 molecule/(100 eV), respectively, which is comparable with the radiation-chemical decomposition yield, taking into account the installation efficiency. |
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