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嵌段共聚酯的合成研究
引用本文:李鑫,仲蕾兰,顾利霞. 嵌段共聚酯的合成研究[J]. 功能高分子学报, 2001, 14(3): 288-293
作者姓名:李鑫  仲蕾兰  顾利霞
作者单位:东华大学纤维改性国家重点实验室!上海200051
摘    要:采用直接酯化法合成了一系列含间苯二甲酸的PEIT-PEG嵌段共聚酯,研究了聚合时间,聚合效率及聚酯的特性粘度与产物中间苯二甲酸含量及共聚酯分子量的关系,得出适于纺丝工艺及工业化生产的共聚酯分子量和间苯二甲酸的含量。

关 键 词:共聚酯 PEIT PEG 聚合效率 特性粘度 聚对苯二甲酸二乙醇酯 聚乙二醇 合成
文章编号:1008-9357(2001)03-0288-05
修稿时间:2001-04-16

Study on Copolymerization of Poly(ethylene terephthalate co-isophthalate)-poly(ethylene glycol)(PEIT-PEG) Copolyester
LI Xin,ZHONG Lei lan,GU Lixia. Study on Copolymerization of Poly(ethylene terephthalate co-isophthalate)-poly(ethylene glycol)(PEIT-PEG) Copolyester[J]. Journal of Functional Polymers, 2001, 14(3): 288-293
Authors:LI Xin  ZHONG Lei lan  GU Lixia
Abstract:A series of block copolyesters based on poly(ethylene terephthalate co isophthalate) poly(ethylene glycol)(PEIT PEG)was prepared by direct esterification poly condensation process. The effects of components together with their molecular weight and contents on copolymerization time, copolymerization efficient and the intrinsic viscosity of the block copolyesters were discussed, by which the spinning grade molecular weight and contents of PEG were concluded.
Keywords:PEIT PEG copolyester  polymerization efficienty  intrinsic viscosity
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