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界面不稳定现象与相间迁移
引用本文:胡学铮,刘俊康,虞学俊,刘松琴.界面不稳定现象与相间迁移[J].物理化学学报,1998(11).
作者姓名:胡学铮  刘俊康  虞学俊  刘松琴
作者单位:无锡轻工业大学化学工程系!无锡214036
摘    要:包含有流动界面的多相体系中的溶质相间迁移在一定条件下可导致表现为界面变形、界面流和多种形式界面运动的不稳定现象.该现象的直接驱动力是界面局部区域出现的张力梯度,表面活性物质在该现象中起重要作用1,2].溶质相间迁移通常可考虑为三步:(1)溶质在原所在相内部向

关 键 词:界面不稳定现象  界面吸附  扩散迁移

Interfacial Instability and Mass Transfer
Hu Xuezheng, Liu Junkang, Yu Xuejun, Liu Songqin.Interfacial Instability and Mass Transfer[J].Acta Physico-Chimica Sinica,1998(11).
Authors:Hu Xuezheng  Liu Junkang  Yu Xuejun  Liu Songqin
Abstract:The interfacial instability due to the transfer of the 1-butanol from water to oil in two systems of 1-butanol oil/water has been studied. The dynamic characteristics of the phenomenon are investigated by analysing the motion of an oil lens deposited at the surface of the aqueous solution of 1-butanol. The interfacial adsorption kinetics based on diffusion-controlled transfer is analysed. It is found that the linear relation between the frequence of the oscillatory motion of the lens and t1/2 is a characteristic relation. The type of the solute transfer in the interfacial instability is discussed by comparing experimental results with the linear characteristics.
Keywords:Solute Marangoni effect  Interfacial adsorption  Diffusion transfer
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