Investigation of n-hexane dehydrocyclization over supported Pt catalyst modified by adsorbed rhenium |
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Authors: | G A Nesterov V M Mastikhin O B Lapina and V A Zakharov |
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Institution: | (1) Central Research Institute for Chemistry of the Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025 Budapest |
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Abstract: | A -Al2O3 supported Re–Pt bimetallic catalyst prepared by electrochemical adsorption has been studied in n-hexane dehydrocyclization, using the slug-pulse method. The activity of the Re–Pt/Al2O3 catalyst treated only in hydrogen was low, but markedly increased by a calcination step before hydrogen treatment. The modified catalyst showed higher activity and increased selectivities for benzene and iso-hexanes than the base Pt/Al2O3 catalyst.
Pd/Pt, -Al2O3, -. Pd–Pt/Al2O3, , , . Pd–Pt/Al2O3 , Pt/Al2O3. |
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