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Synthesis and study of RbSrR(MoO4)3 ternary molybdates (R = Nd, Sm, Eu, Gd) with scheelite-like structure
Authors:N M Kozhevnikova
Institution:1190. Baikal Institute of Nature Management, Siberian Branch, Russian Academy of Sciences, Ulan-Ude, Buryat Republic, Russia
Abstract:Phase relations in the subsolidus region of the Rb2MoO4-SrMoO4-R2(MoO4)3 systems (where R = Nd, Sm, Eu, Gd) were studied by IR spectroscopy, X-ray diffraction analysis, and differential thermal analysis. RbSrR(MoO4)3 ternary molybdates (where R = Nd, Sm, Eu, Gd) with scheelite-like structures belonging to the monoclinic crystal system (space group P21/n) were synthesized. Their unit cell parameters were determined; IR and Raman spectra were characterized.
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