Crystal structure of bis(2-(2-thiazolylazo)-4-methylphenol)cobalt(III)chloride. |
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| Authors: | Lumduan Mangsup Sutatip Siripaisarnpipat Narongsuk Chaichit |
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| Institution: | Laboratory of Crystallography and Gemmology, Department of Chemistry, Faculty of Science, Kasetsart University, Thailand. |
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| Abstract: | The reaction between CoCl2 x 6H2O and 2-1-(2-thiazolylazo)-p-cresol (TAC) in acetone resulted in six coordinated cobalt(III) complex, Co(TAC)2]Cl3. Two TAC ligands coordinate with cobalt ion forming four five membered chelate rings. The cobalt ion is octahedrally coordinated by a phenolic oxygen, azo nitrogen and nitrogen in thiazole rings. Three chloride ions are disordered. |
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