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SYNTHESIS AND STRUCTURE OF MACROPOROUS MA-TMPTA COPOLYMERS AND THEIR APPLICATION IN ADSORPTION OF FLAVONOIDS FROM GINKGO LEAVES EXTRACT
作者姓名:SHI Zuoqing  XU Mancai  FENG Lili  XU Mingcheng  SHI Rongfu  FAN Yunge  HE Binglin
作者单位:SHI Zuoqing,XU Mancai,FENG Lili,XU Mingcheng,SHI Rongfu,FAN Yunge,HE Binglin ( The State Key Laboratory of Functional Polymeric Materials for Adsorption and Separation. Institute of polymer Chemistry,Nankai University Tianjin 300071
基金项目:Supported by the National Natural Science Foundation of China !(Grant No. 29574164)
摘    要:1 INTRODUCTIONAdsorption by macroporous polymeric adsorbents is one of tile important methods inpurification of ginkgo leaves extract ill. Amberlite XAD-7, a macroporous polymeric adsorbentbased on methyl methacrylate - trimethylolpropane triacrylate copolymer, was reported to use inadsorptive purification of ginkgo leaves extract and other natural products containing flavonoidsfi.3]. Interaction between the adsorbent and flavonoids is based on hydrogen bonding between theester carbonyl-…


SYNTHESIS AND STRUCTURE OF MACROPOROUS MA-TMPTA COPOLYMERS AND THEIR APPLICATION IN ADSORPTION OF FLAVONOIDS FROM GINKGO LEAVES EXTRACT
SHI Zuoqing,XU Mancai,FENG Lili,XU Mingcheng,SHI Rongfu,FAN Yunge,HE Binglin.SYNTHESIS AND STRUCTURE OF MACROPOROUS MA-TMPTA COPOLYMERS AND THEIR APPLICATION IN ADSORPTION OF FLAVONOIDS FROM GINKGO LEAVES EXTRACT[J].离子交换与吸附(英文版),2000(1).
Authors:SHI Zuoqing  XU Mancai  FENG Lili  XU Mingcheng  SHI Rongfu  FAN Yunge  HE Binglin
Abstract:Spherical macroporous copolymers of methyl acrylate and trimethylolpropane triacrylate with different surface and pore structure were synthesized via suspension polymerization. and their surface and pore structure were characterized by measurements of surface area, apparent density and skeleton density and calculation of average pore diameter The results revealed that crosslinking degree and porogent determined the physical structure of these copolymers. Some of the copolymers were applied to adsorptive purification of ginkgo leaves extract to enhance the content of flavonoids, the results showed that most of the copolymers could be used to increase the flavonoids content.
Keywords:Methyl acrylate-trimethylolpropane triacrylate copolymer  Flavonol  glycosides  Adsorption
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