Synthesis of vinylcyclopentanes via samarium(II) mediated tandem reactions |
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| Authors: | Mounira Bent Sadok Ferjani |
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| Institution: | Département de chimie et de biochimie, Université du Québec à Montréal, Case postale 8888, succursale Centre-Ville, Montréal, Québec, Canada H3C 3P8 |
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| Abstract: | In the presence of either visible light or HMPA, SmI2 reacts with some carbohydrate derived ω-iodoallylic alcohols, and their acetylated derivatives, to give vinylcyclopentanediol and vinylcyclopentanetriol derivatives. |
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| Keywords: | Alkenyl halides Cyclisation Samarium and compounds Tandem or sequential reactions |
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