Palladium charcoal-catalyzed deprotection of O-allylphenols |
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| Authors: | Miyuki Ishizaki Osamu Hoshino |
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| Affiliation: | Faculty of Pharmaceutical Sciences, Tokyo University of Science, 2641, Yamazaki, Noda-shi, Chiba 278-8510, Japan |
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| Abstract: | Allyl aryl ethers can be easily cleaved by the use of 10% Pd/C under mild and basic conditions. The present reaction would involve a SET process rather than a π-allyl-palladium complex. The scope and limitation of this new deprotective methodology is also described. |
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| Keywords: | Allyl aryl ethers Deprotection Palladium charcoal SET process |
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