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Oxime-based methods for synthesis of stereodefined acyclic polyfunctionalized δ-azido-nitriles and 5-substituted isoxazoles from carbohydrate derivatives |
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| Authors: | Pietro Passacantilli Daniela Pigini Antonella Squarcia |
| Institution: | Dipartimento di Chimica and Istituto di Chimica Biomolecolare del CNR, Sezione di Roma, Università ‘La Sapienza’, Piazzale Aldo Moro 5, 00185 Rome, Italy |
| Abstract: | Hydroxylamine-mediated syntheses of stereodefined acyclic polyfunctionalized δ-azido-nitriles and 5-substituted isoxazoles, bearing a differentially protected glycerol moiety, from 2-deoxysugars and glycals are described. |
| Keywords: | 2-Deoxycarbohydrates Stereodefined acyclic polyfunctional δ-azido-nitriles Glycals Isoxazoles Glycerols |
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