Oxidative nucleophilic substitution of hydrogen in nitroarenes with trifluoromethyl carbanions. Synthesis of trifluoromethyl phenols |
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| Authors: | Marek Surowiec |
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| Affiliation: | Institute of Organic Chemistry, Polish Academy of Sciences, ul. Kasprzaka 44/52, PL-01-224 Warsaw POB 58, Poland |
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| Abstract: | Trifluoromethyl carbanions generated from the Ruppert reagent and TASF add to highly electron-deficient nitroarenes to produce σH adducts subsequently oxidized with dimethyldioxirane to substituted trifluoromethyl phenols. |
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| Keywords: | Ruppert reagent Nitroarenes Carbanions Dimethyldioxirane Phenols |
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