Synthesis of complex alkoxyamines using a polymer-supported N-hydroxyphthalimide |
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| Authors: | Shun Su John A. Porco Jr. |
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| Affiliation: | Department of Chemistry and Center for Chemical Methodology and Library Development, Metcalf Center for Science and Engineering, Boston University, 590 Commonwealth Avenue, Boston, MA 02215-2507, USA |
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| Abstract: | The synthesis of a polymer-supported N-hydroxyphthalimide is described. The polystyrene-bound N-hydroxyphthalimide resin 1 has been used to prepare complex alkoxyamines exhibiting both stereochemical and positional diversity. Methods for efficient condensation of complex alkoxyamines with aldehydes and ketones are also outlined. |
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| Keywords: | Polymer-supported N-Hydroxyphthalimide Alkoxyamine Stereochemical diversity Positional diversity |
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