Poly(ε-caprolactone) macroligands with β-diketonate binding sites: synthesis and coordination chemistry |
| |
| Authors: | Jessica L. Bender |
| |
| Affiliation: | Department of Chemistry, University of Virginia, McCormick Road, PO Box 400319, Charlottesville, VA 22904-4319, USA |
| |
| Abstract: | Dibenzoylmethane (dbm) initiators with one and two alcohol sites were used to generate dbm end-functionalized and dbm-centered poly(ε-caprolactone) macroligands (dbmPCL and dbmPCL2) with low polydispersities (∼1.1). Chelation of polymeric ligands to metal ions (Eu3+, Fe3+, Ni2+ and Cu2+) produced metal-centered star polymers, which were characterized by UV-vis and fluorescence spectroscopy, as well as gel permeation chromatography. |
| |
| Keywords: | Metallopolymer Poly(caprolactone) β-Diketonate Europium |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
