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Assembling tetrapyrrole derivatives through axial coordination
Authors:Michael T.M. Choi
Affiliation:Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, China
Abstract:Bis(4-pyridinolato) silicon(IV) phthalocyanine (1) binds with a series of zinc(II) tetrapyrrole derivatives with the two pyridyl ligands forming the corresponding 1:2 or 1:1 molecular assemblies. The molecular structure of the first axially linked trinuclear phthalocyanine-porphyrin array has also been determined.
Keywords:Phthalocyanines   Porphyrins   Axial coordination
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