Enantioselective oxidative coupling of methyl 3-hydroxy-2-naphthoate using mono-N-alkylated octahydrobinaphthyl-2,2′-diamine ligand |
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Authors: | Kyoung Hoon Kim |
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Institution: | Department of Chemistry, Korea University, Seoul 136-701, South Korea |
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Abstract: | Mono-N-alkylated octahydrobinaphthyl-2,2′-diamine (H8-BINAM) chiral ligands were employed in the catalytic and asymmetric oxidative coupling of methyl 3-hydroxy-2-naphthoate to the corresponding binaphthol derivative. The diamine ligand with one N-(3-pentyl) group shows highest enantioselectivity in the biaryl coupling among other BINAM derivatives, and the coupling reaction proceeds faster than the reactions using alkanediamine ligands. |
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Keywords: | Catalytic Asymmetric Oxidation Biaryl Coupling Binaphthol |
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