The facile preparation of alkenyl metathesis synthons |
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Authors: | Travis W. Baughman |
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Affiliation: | The George and Josephine Butler Polymer Research Laboratory, Department of Chemistry, University of Florida, PO Box 117200, Gainesville, FL 32605, USA |
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Abstract: | We report synthetic methodology allowing the preparation of any length alkenyl halide from inexpensive starting reagents. Standard organic transformations were used to prepare straight chain α-olefin halides in excellent overall yields with no detectable olefin isomerization and full recovery of any unreacted starting material. Reported transformations can be used for the selective incorporation of pure α-olefin metathesis sites in highly functionalized molecules. |
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Keywords: | α-Olefin Cross-metathesis Alkenyl halide ADMET Metathesis |
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