Synthesis and structural characterisation of a cationic trinuclear organobismuth complex with an unprecedented coordination mode of hydrotris(2-mercaptoimidazolyl)borate ligands |
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| Authors: | Bao Ming Hayashi Teruyuki Shimada Shigeru |
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| Institution: | National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan. |
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| Abstract: | A new coordination mode of hydrotris(2-mercaptoimidazolyl)borate ligands was found in the reaction of Na(Tm(tBu))] with Me(2)BiCl to form a trinuclear organobismuth complex (Me(2)Bi)(3)(Tm(tBu))(2)](+)Me(2)BiCl(2)](-)(Tm(tBu)= hydrotris(2-mercapto-1-tert-butylimidazolyl)borate). |
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