Specificity of states of Cu2+ ions in ZSM zeolites due to the cooperative Jahn-Teller effect |
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| Authors: | V F Anufrienko V A Poluboyarov L A Vostrikova and K G Ione |
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| Institution: | (1) Institute of Catalysis, Novosibirsk, USSR |
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| Abstract: | Crystalline silicate of ZSM zeolite structure was synthesized via hydrothermal crystallization at large contents of copper. ESR spectra of Cu2+ ions stabilized in this system are determined by the specific ordering due to the cooperative Jahn-Teller effect of Cu2+ ions with the dx
2–y2 ground state.
                  423°   ZSM      .       Cu(II),  ,     - Cu2+ cdx2–y2— .
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