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Luminescence behavior of Tb ions in transparent glass and glass-ceramics containing CaF2 nanocrystals
Authors:Xin-yuan Sun  Mu Gu  Shi-ming Huang  Xiao-lin Liu  Chen Ni
Institution:a Pohl Institute of Solid State Physics, Laboratory of Waves & Microstructure Materials, Tongji University, 200092 Shanghai, PR China
b Department of Physics, Jinggangshan University, Ji’an 343009, PR China
Abstract:Transparent glass-ceramics have been fabricated by heat treatment with 1.0 mol% Tb2O3-doped 45SiO2-20Al2O3-10CaO-25CaF2 aluminosilicate glass. The precipitated crystalline phase in the glass-ceramics is CaF2 nanocrystals with a size of 15-27 nm and dispersed in the amorphous phase. Both photo- and radioluminescence measurements show that the increase of Tb3+ 545 nm line intensity by a factor of 4 and 3.5 is obtained in glass-ceramics with respect to the as-made glass, respectively.
Keywords:Tb3+-doped oxyfluoride glass  CaF2 nanocrystals  Transparent glass-ceramics  Luminescence  X-ray excited luminescence
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