Thermal decomposition kinetics of iron(III), cobalt(II), nickel(II) and copper(II) complexes of a Schiff base derived from quinoxaline-2-carboxaldehyde and glycine |
| |
| Authors: | R. Sreekala and K. K. Mohammed Yusuff |
| |
| Affiliation: | (1) Department of Applied Chemistry, Cochin University of Science and Technology, 682 022 Kochi, India |
| |
| Abstract: | Quinoxaline-2-carboxalideneglycine complexes of iron(III), cobalt(II), nickel(II) and copper(II) complexes were subjected to a systematic TG/DTG analysis. The decomposition process consists of two stages for all these complexes. Kinetic parameters were evaluated for each of these stages using the Coats-Redfern equation. The rate of decomposition at the second stage seems to have a bearing on the catalytic effect of the metal oxides formed during this stage.
             -2-       (III)    (II), (II)  (II)     / .    .  -   .  , -, ,  .
|
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
