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AlPO4-5分子筛与NaF反应机理的研究
引用本文:侯军,翟纯.AlPO4-5分子筛与NaF反应机理的研究[J].波谱学杂志,1988,5(4):379-384.
作者姓名:侯军  翟纯
作者单位:北京石油化工科学研究院
摘    要:本文用XRD和31P NMR研究以Et3N为模板剂合成的AlPO4-5分子筛与NaF的反应机理。研究结果表明P、Al在AlPO4-5分子筛中是严格有序交替排列的,且这种排列与合成中所用模板剂无关,并提出了上述反应的机理。

收稿时间:1987-06-27

THE STUDY OF THE REACTION MECHANISM OF AIP0_4-5 MOLECULAR SIEVE WITH NAF
Hou Jun and Zhai Chun.THE STUDY OF THE REACTION MECHANISM OF AIP0_4-5 MOLECULAR SIEVE WITH NAF[J].Chinese Journal of Magnetic Resonance,1988,5(4):379-384.
Authors:Hou Jun and Zhai Chun
Institution:Research Institute of Petroleum Processing
Abstract:XRD and multinuclear liquid state NMR techniques were used to study the reaction mechanism of AlP04-5 molecular sieve (synthesized by using Et3N as template ) with NaF. It was shown that P and Al are strictly alternative in the framework of AlP04-5 molecular sieve; and that their ordering in AlP04-5 molecular sieve has nothing to do with the templates used.The mechanism of the above reaction was proposed.
Keywords:AlP0_4-5  NMR  Molecular Sieve  
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